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Наносистеми, наноматеріали, нанотехнології. - 2012. - Т. 10, Вип. 1. - С. 123-133. - Режим доступу: http://nbuv.gov.ua/UJRN/Nano_2012_10_1_17","author":[{"citation:authorName":"Smolyak Svitlana","citation:authorAffiliation":"SPM&RS Centre","authorIdentifierScheme":"ORCID","authorIdentifier":"0000-0002-5403-4092"},{"citation:authorName":"Karbivskyy Volodymyr","citation:authorAffiliation":"SPM&RS Centre","authorIdentifierScheme":"ORCID","authorIdentifier":"0000-0003-0412-2788"}],"publication":{"publicationCitation":"V. L. Karbivskyy, S. S. Smolyak, Yu. A. Zagorodniy, V. H. Kasiyanenko. Electronic structure peculiarities of disordered of Mn and Co diphosphates. 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During the experiment, the vacuum in the analytical chamber was 10-7 Pa, the accuracy of the electrons binding energy definition - 0.1 eV. The samples were in the form of dispersed powder deposited on an aluminum substrate.\nBecause the investigated samples are insulators, the emission of electrons during the spectrum acquisition led to the formation of a positive electrical charge on their surface and to an essential shift of corresponding lines. Calibration of X-ray photoelectron spectra taking into account the accumulated charge, were carried by the binding energy of 1s-level of carbon, which was accepted equal to 284.4 eV.\nThe synthesis of the samples was carried out by Candidate of Chemical Sciences Tkachova N.V.","relatedDatasets":"Smolyak, Svitlana; Karbivskyy Volodymyr, 2025, \"Study of the electronic structure of Mn2-хCoxP2O7·5H2O at x=0.6, using X-ray photoelectron spectroscopy\", https://doi.org/10.48788/DVUA/RROGBK","contributor":[{"citation:contributorType":"Research Group","citation:contributorName":"SPM&RS Centre"},{"citation:contributorType":"Hosting Institution","citation:contributorName":"Kurdyumov Institute for Metal Physics of the NAS of Ukraine"}],"@id":"https://doi.org/10.48788/DVUA/0YSLVZ","@type":["ore:Aggregation","schema:Dataset"],"schema:version":"1.0","schema:name":"Study of Mn2-хCoxP2O7·5H2O, at x=0, using X-ray photoelectron spectroscopy","schema:dateModified":"2025-09-26 12:39:23.967","schema:datePublished":"2025-09-26","schema:creativeWorkStatus":"RELEASED","schema:license":"http://creativecommons.org/licenses/by/4.0","dvcore:fileTermsOfAccess":{"dvcore:fileRequestAccess":true},"schema:includedInDataCatalog":"DataverseUA","schema:isPartOf":{"schema:name":"SPM&RS Centre","@id":"https://opendata.nas.gov.ua/dataverse/spm","schema:description":"The collective use centre \"Centre of scanning probe microscopy and resonance spectroscopy\" (SPM&RS-Centre) was created in 2012 in the structure of the G. 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