{"dcterms:modified":"2026-03-27","dcterms:creator":"DataverseUA","@type":"ore:ResourceMap","schema:additionalType":"Dataverse OREMap Format v1.0.0","dvcore:generatedBy":{"@type":"schema:SoftwareApplication","schema:name":"Dataverse","schema:version":"6.2","schema:url":"https://github.com/iqss/dataverse"},"@id":"https://opendata.nas.gov.ua/api/datasets/export?exporter=OAI_ORE&persistentId=https://doi.org/10.48788/DVUA/MNVHJZ","ore:describes":{"citation:keyword":[{"citation:keywordValue":"X-ray Photoelectron Spectroscopy","citation:keywordVocabulary":"Montana State University","citation:keywordVocabularyURI":"https://serc.carleton.edu/msu_nanotech/methods/xps.html"},{"citation:keywordValue":"Electronic structure","citation:keywordVocabulary":"mscr-vocabularies","citation:keywordVocabularyURI":"https://mscr-vocabularies-test.2.rahtiapp.fi/terminology/6cbaa431-66bc-4555-a455-fe0ba6375cb3/concept/0aa17eef-5097-48af-a69f-86c469f645b4"},{"citation:keywordValue":"X-ray Photoelectron Spectroscopy","citation:keywordVocabulary":"mscr-vocabularies","citation:keywordVocabularyURI":"https://mscr-vocabularies-test.2.rahtiapp.fi/terminology/6cbaa431-66bc-4555-a455-fe0ba6375cb3/concept/3d7b2957-343c-4831-ba79-a00b0c3d3285"},{"citation:keywordValue":"Electronic structure","citation:keywordVocabulary":"Nature","citation:keywordVocabularyURI":"https://www.nature.com/subjects/electronic-structure-of-atoms-and-molecules"},{"citation:keywordValue":"Nuclear magnetic resonance","citation:keywordVocabulary":"Abragam, A. The principles of nuclear magnetism.  Oxford, Clarendon Press, 1962"},{"citation:keywordValue":"Bioactive glass","citation:keywordVocabulary":"Wikipedia","citation:keywordVocabularyURI":"https://en.wikipedia.org/wiki/Bioactive_glass"}],"author":[{"citation:authorName":"Smolyak Svitlana","citation:authorAffiliation":"SPM&RS Centre","authorIdentifierScheme":"ORCID","authorIdentifier":"0000-0002-5403-4092"},{"citation:authorName":"Karbivskyy Volodymyr","citation:authorAffiliation":"SPM&RS Centre","authorIdentifierScheme":"ORCID","authorIdentifier":"0000-0003-0412-2788"},{"citation:authorName":"Zagorodniy Yuriy","citation:authorAffiliation":"I.M.Frantsevich Institute for Problems in Material Science of the NAS. of Ukraine,Kyiv, Ukraine","authorIdentifierScheme":"ORCID","authorIdentifier":"0000-0002-0404-5041"}],"citation:dsDescription":{"citation:dsDescriptionValue":"The electronic structure and structural characteristics of 5% Ga-doped sol-gel bioactive glass (type 45S5) were studied by X-ray photoelectron spectroscopy (XPS) and nuclear magnetic resonance (NMR) methods.  ³¹P NMR spectra of bioactive materials indicate the formation of both isolated (PO4)3- and Si-O-P bonds, etc. in them, the relative part of which is proportional to the integral intensity of the corresponding NMR line.\nThe synthesis of the samples was carried out by Doctor of Chemical Sciences Vitaliy A. Dubok."},"publication":{"publicationCitation":"Svitlana S. Smolyak, Volodymyr L. Karbivskyy, Vitaliy A. Dubok, Volodymyr S. Chornyi, Olexander V. Shynkaruk, Anastas O. Romansky, Lyubov I. Karbivska. New bone substitute based on nanodispersed calcium ceramics. Ukr. Bioorg. Acta, 2023, Vol. 18, N 1, p. 42-50.","publicationIDType":"doi","publicationIDNumber":"https://bioorganica.com.ua/index.php/journal/article/view/58","publicationURL":"https://bioorganica.com.ua/index.php/journal/article/view/58"},"citation:datasetContact":{"citation:datasetContactName":"Smolyak, Svitlana","citation:datasetContactAffiliation":"SPM&RS Centre","citation:datasetContactEmail":"sssmolyak@gmail.com"},"citation:notesText":"X-ray  photoelectron spectra (XPS) were obtained on a JEOL JSPM-4610 photoelectron spectrometer using a non-monochromatic MgKα  X-ray source (1253.6eV). During the experiment, the vacuum in the analytical chamber  was   10⁻⁷ Pa, and the electron binding energy determination accuracy was 0.1. The samples for the study were prepared as dispersed powders deposited on an aluminum substrate.  A  thin gold layer was deposited on the insulating surface of the sample to prevent charge accumulation during the experiment. The X-ray photoelectron spectra were calibrated by the binding energy of Au 4f lines, which enabled high-precision determination of the electron binding energy for the elements in the sample. \nNuclear magnetic resonance (NMR)  spectra  were recorded  on  a  Bruker  Avance400  spectrometer  at  room  temperature.  ³¹P NMR  spectra were obtained  for static  samples (at a frequency 161,97  MHz). The  magnetic  field  was referenced  by  the  H₃PO₄ spectrum,  which  was  used  as  an external standard for magnetic field calibration.","dateOfDeposit":"2026-03-23","title":"X-ray photoelectron and Nuclear Magnetic Resonance studies of sol-gel glass doped with 5% Ga","subject":"Physics","citation:depositor":"Smolyak Svitlana","contributor":{"citation:contributorType":"Research Group","citation:contributorName":"SPM&RS Centre"},"citation:series":{"citation:seriesName":"Spectroscopy dataset"},"citation:producer":{"citation:producerName":"G. V. Kurdyumov Institute for Metal Physics","citation:producerAffiliation":"N.A.S. of Ukraine","citation:producerAbbreviation":"IMP","citation:producerURL":"https://www.imp.kiev.ua/","citation:producerLogoURL":"https://www.imp.kiev.ua/img/header_ua.jpg"},"grantNumber":{"citation:grantNumberAgency":"NAS of Ukraine"},"language":"English","citation:productionPlace":"Kyiv, Ukraine","kindOfData":"Spectra – processed experimental spectrum","citation:productionDate":"2019","@id":"https://doi.org/10.48788/DVUA/MNVHJZ","@type":["ore:Aggregation","schema:Dataset"],"schema:version":"1.0","schema:name":"X-ray photoelectron and Nuclear Magnetic Resonance studies of sol-gel glass doped with 5% Ga","schema:dateModified":"2026-03-27 13:46:28.147","schema:datePublished":"2026-03-27","schema:creativeWorkStatus":"RELEASED","schema:license":"http://creativecommons.org/licenses/by/4.0","dvcore:fileTermsOfAccess":{"dvcore:termsOfAccess":"Contact owner","dvcore:fileRequestAccess":true},"schema:includedInDataCatalog":"DataverseUA","schema:isPartOf":{"schema:name":"SPM&RS Centre","@id":"https://opendata.nas.gov.ua/dataverse/spm","schema:description":"The collective use centre \"Centre of scanning probe microscopy and resonance spectroscopy\" (SPM&RS-Centre) was created in 2012 in the structure of the G. V. Kurdyumov Institute for Metal Physics National Academy of Sciences of Ukraine for the most rational use of unique equipment – ultrahigh vacuum scanning probe microscope JSPM-4610 of JEOL company and NMR and EPR spectrometers of BRUKER company. The main mission of SPM&RS-Centre is to provide the capabilities to the NAS of Ukraine scientific community to conduct investigations on the modern level devices, serviced by qualified personnel, who can maintain the equipment in high-quality working order and provide advisory services.","schema:isPartOf":{"schema:name":"G.V. Kurdyumov Institute for Metal Physics of the N.A.S. of Ukraine","@id":"https://opendata.nas.gov.ua/dataverse/imp","schema:description":"<p><b>G. V. Kurdyumov Institute for Metal Physics of the N.A.S. of Ukraine (hereinafter, Institute) was founded in 1945. It is one of the largest scientific centres of fundamental research in the field of metal physics in Ukraine and Europe.</b></p>\n<p>The scientists of the Institute carry out research on four <b>basic scientific directions:</b></p>\n\n<li>Electronic structure and properties of metals and metal-based compounds\n<li>Nanoscale and nanostructured systems\n<li>Atomic constitution of metals and metal-containing heterophase structures\n<li>Physics of strength and plasticity of metals and alloys","schema:isPartOf":{"schema:name":"DataverseUA","@id":"https://opendata.nas.gov.ua/dataverse/dataverseua","schema:description":"Data repository of the institutes of the National Academy of Sciences of Ukraine."}}},"ore:aggregates":[{"schema:description":" ³¹P NMR static spectra of sol-gel bioactive glass doped with 5% Ga. Room temperature, collected at frequency 161,97 MHz","schema:name":"31P_NMR.jpeg","dvcore:restricted":false,"schema:version":3,"dvcore:datasetVersionId":94,"dvcore:categories":["Image"],"@id":"https://opendata.nas.gov.ua/file.xhtml?fileId=1102","schema:sameAs":"https://opendata.nas.gov.ua/api/access/datafile/1102","@type":"ore:AggregatedResource","schema:fileFormat":"image/jpeg","dvcore:filesize":71935,"dvcore:storageIdentifier":"local://19d2b5529a7-c2e6f676d617","dvcore:rootDataFileId":-1,"dvcore:checksum":{"@type":"MD5","@value":"20f06c770d7643a35dd38ee3f19a50fd"}},{"schema:description":"X-ray photoelectron Ca 2р spectrum of sol-gel bioactive glass doped with 5% Ga","schema:name":"Ca2p.emf","dvcore:restricted":false,"schema:version":2,"dvcore:datasetVersionId":94,"dvcore:categories":["Image"],"@id":"https://opendata.nas.gov.ua/file.xhtml?fileId=1096","schema:sameAs":"https://opendata.nas.gov.ua/api/access/datafile/1096","@type":"ore:AggregatedResource","schema:fileFormat":"image/emf","dvcore:filesize":9876,"dvcore:storageIdentifier":"local://19d1b179d7e-9cc06466bc55","dvcore:rootDataFileId":-1,"dvcore:checksum":{"@type":"MD5","@value":"c792562c5daa48e7ecb3161c921aa2bc"}},{"schema:description":"Deconvolution of Ca 2р spectrum of sol-gel bioactive glass doped with 5% Ga","schema:name":"Ca2p_fitting.jpg","dvcore:restricted":true,"schema:version":4,"dvcore:datasetVersionId":94,"dvcore:categories":["Image"],"@id":"https://opendata.nas.gov.ua/file.xhtml?fileId=1094","schema:sameAs":"https://opendata.nas.gov.ua/api/access/datafile/1094","@type":"ore:AggregatedResource","schema:fileFormat":"image/jpeg","dvcore:filesize":30615,"dvcore:storageIdentifier":"local://19d1b151ec3-9e0e3a2c3009","dvcore:rootDataFileId":-1,"dvcore:checksum":{"@type":"MD5","@value":"0493d8d33c01d713816a182bccefa703"}},{"schema:description":"XPS spectra of Ca 2р region of sol-gel bioactive glass doped with 5% Ga","schema:name":"Ca2p_spectrum.txt","dvcore:restricted":false,"schema:version":2,"dvcore:datasetVersionId":94,"dvcore:categories":["Data"],"@id":"https://opendata.nas.gov.ua/file.xhtml?fileId=1095","schema:sameAs":"https://opendata.nas.gov.ua/api/access/datafile/1095","@type":"ore:AggregatedResource","schema:fileFormat":"text/plain","dvcore:filesize":5147,"dvcore:storageIdentifier":"local://19d1b194c98-dfdb5648569d","dvcore:rootDataFileId":-1,"dvcore:checksum":{"@type":"MD5","@value":"a8479b88423c0bc7095968bc496bd4d9"}},{"schema:description":"XPS spectra of O1s region, sol-gel bioactive glass doped with 5% Ga","schema:name":"O1s.emf","dvcore:restricted":false,"schema:version":3,"dvcore:datasetVersionId":94,"dvcore:categories":["Image"],"@id":"https://opendata.nas.gov.ua/file.xhtml?fileId=1101","schema:sameAs":"https://opendata.nas.gov.ua/api/access/datafile/1101","@type":"ore:AggregatedResource","schema:fileFormat":"image/emf","dvcore:filesize":10124,"dvcore:storageIdentifier":"local://19d1b1d9d95-e96b91a48081","dvcore:rootDataFileId":-1,"dvcore:checksum":{"@type":"MD5","@value":"1e0d57534ba2c5d440f53a3b08e7add8"}},{"schema:description":"Deconvolution of O1s spectra of sol-gel bioactive glass doped with 5% Ga","schema:name":"O1s_fitting.jpg","dvcore:restricted":false,"schema:version":3,"dvcore:datasetVersionId":94,"dvcore:categories":["Image"],"@id":"https://opendata.nas.gov.ua/file.xhtml?fileId=1098","schema:sameAs":"https://opendata.nas.gov.ua/api/access/datafile/1098","@type":"ore:AggregatedResource","schema:fileFormat":"image/jpeg","dvcore:filesize":34943,"dvcore:storageIdentifier":"local://19d1b1b992f-065cdc4ec205","dvcore:rootDataFileId":-1,"dvcore:checksum":{"@type":"MD5","@value":"2195a11aa0de44efea687602ef17299c"}},{"schema:description":"XPS spectra of O1s region, sol-gel bioactive glass doped with 5% Ga","schema:name":"O1s_spectrum.txt","dvcore:restricted":false,"schema:version":2,"dvcore:datasetVersionId":94,"dvcore:categories":["Data"],"@id":"https://opendata.nas.gov.ua/file.xhtml?fileId=1097","schema:sameAs":"https://opendata.nas.gov.ua/api/access/datafile/1097","@type":"ore:AggregatedResource","schema:fileFormat":"text/plain","dvcore:filesize":5486,"dvcore:storageIdentifier":"local://19d1b1e5654-8e0ad7616353","dvcore:rootDataFileId":-1,"dvcore:checksum":{"@type":"MD5","@value":"186e612475cfcbfd9a2f0cc1044f41c3"}},{"schema:description":"Text file containing information related to the directory content","schema:name":"ReadMe_sol-gel glass_doped_5% Ga.txt","dvcore:restricted":false,"schema:version":1,"dvcore:datasetVersionId":94,"dvcore:categories":["Data","Documentation"],"@id":"https://opendata.nas.gov.ua/file.xhtml?fileId=1103","schema:sameAs":"https://opendata.nas.gov.ua/api/access/datafile/1103","@type":"ore:AggregatedResource","schema:fileFormat":"text/plain","dvcore:filesize":5635,"dvcore:storageIdentifier":"local://19d2b660ca5-1175e86d1fe8","dvcore:rootDataFileId":-1,"dvcore:checksum":{"@type":"MD5","@value":"9ec2d1163d7b7274b54f1a48f8ea5080"}},{"schema:description":"XPS spectra of Si 2p region, sol-gel bioactive glass doped with 5% Ga","schema:name":"Si2p.emf","dvcore:restricted":false,"schema:version":2,"dvcore:datasetVersionId":94,"dvcore:categories":["Image"],"@id":"https://opendata.nas.gov.ua/file.xhtml?fileId=1099","schema:sameAs":"https://opendata.nas.gov.ua/api/access/datafile/1099","@type":"ore:AggregatedResource","schema:fileFormat":"image/emf","dvcore:filesize":10232,"dvcore:storageIdentifier":"local://19d1b1eeac2-4d521d9fb356","dvcore:rootDataFileId":-1,"dvcore:checksum":{"@type":"MD5","@value":"3cce48d86c8fb74256dbf54560d4699b"}},{"schema:description":"XPS spectra of Si 2p region, sol-gel bioactive glass doped with 5% Ga","schema:name":"Si2p_spectrum.txt","dvcore:restricted":false,"schema:version":2,"dvcore:datasetVersionId":94,"dvcore:categories":["Data"],"@id":"https://opendata.nas.gov.ua/file.xhtml?fileId=1100","schema:sameAs":"https://opendata.nas.gov.ua/api/access/datafile/1100","@type":"ore:AggregatedResource","schema:fileFormat":"text/plain","dvcore:filesize":4326,"dvcore:storageIdentifier":"local://19d1b1f82d8-49f70a038dc6","dvcore:rootDataFileId":-1,"dvcore:checksum":{"@type":"MD5","@value":"82cd1bb87d9a64123c49d68faadd53bc"}}],"schema:hasPart":["https://opendata.nas.gov.ua/file.xhtml?fileId=1102","https://opendata.nas.gov.ua/file.xhtml?fileId=1096","https://opendata.nas.gov.ua/file.xhtml?fileId=1094","https://opendata.nas.gov.ua/file.xhtml?fileId=1095","https://opendata.nas.gov.ua/file.xhtml?fileId=1101","https://opendata.nas.gov.ua/file.xhtml?fileId=1098","https://opendata.nas.gov.ua/file.xhtml?fileId=1097","https://opendata.nas.gov.ua/file.xhtml?fileId=1103","https://opendata.nas.gov.ua/file.xhtml?fileId=1099","https://opendata.nas.gov.ua/file.xhtml?fileId=1100"]},"@context":{"author":"http://purl.org/dc/terms/creator","authorIdentifier":"http://purl.org/spar/datacite/AgentIdentifier","authorIdentifierScheme":"http://purl.org/spar/datacite/AgentIdentifierScheme","citation":"https://dataverse.org/schema/citation/","contributor":"http://purl.org/dc/terms/contributor","dateOfDeposit":"http://purl.org/dc/terms/dateSubmitted","dcterms":"http://purl.org/dc/terms/","dvcore":"https://dataverse.org/schema/core#","grantNumber":"https://schema.org/sponsor","kindOfData":"http://rdf-vocabulary.ddialliance.org/discovery#kindOfData","language":"http://purl.org/dc/terms/language","ore":"http://www.openarchives.org/ore/terms/","publication":"http://purl.org/dc/terms/isReferencedBy","publicationCitation":"http://purl.org/dc/terms/bibliographicCitation","publicationIDNumber":"http://purl.org/spar/datacite/ResourceIdentifier","publicationIDType":"http://purl.org/spar/datacite/ResourceIdentifierScheme","publicationURL":"https://schema.org/distribution","schema":"http://schema.org/","subject":"http://purl.org/dc/terms/subject","title":"http://purl.org/dc/terms/title"}}