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L. Karbivskyy, S. S. Smolyak, Yu. A. Zagorodniy, V. H. Kasiyanenko. Electronic structure peculiarities of disordered of Mn and Co diphosphates. 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During the experiment, the vacuum in the analytical chamber was 10-7 Pa, the accuracy of the electrons binding energy definition - 0.1 eV. The samples were in the form of dispersed powder deposited on an aluminum substrate. Because the investigated samples are insulators, the emission of electrons during the spectrum acquisition led to the formation of a positive electrical charge on their surface and to an essential shift of corresponding lines. Calibration of X-ray photoelectron spectra taking into account the accumulated charge, were carried by the binding energy of 1s-level of carbon, which was accepted equal to 284.4 eV. The synthesis of the samples was carried out by Candidate of Chemical Sciences Tkachova N.V.","dateOfDeposit":"2025-10-28","citation:depositor":"Smolyak Svitlana","title":"X-ray photoelectron spectroscopic study of the electronic structure of Mn₂₋ₓCoₓP₂O₇·5H₂O, at x=1.0","subject":"Physics","contributor":{"citation:contributorType":"Research Group","citation:contributorName":"SPM&RS Centre"},"relatedDatasets":"Smolyak Svitlana; Karbivskyy Volodymyr, 2025, \"Study of Mn₂₋ₓCoₓP₂O₇·5H₂O, at x=0, using X-ray photoelectron spectroscopy\", https://doi.org/10.48788/DVUA/0YSLVZ, DataverseUA","citation:relatedMaterial":"В. Л. Карбовский, С. С. Смоляк, Ю. А. Загородний, В. Х. Касияненко, Н. В. Ткачова, О. П. Димитриев. Колебательные спектры и термические превращения дифосфатов Mn₂₋ₓCoₓP₂O₇·5H₂O. Наносистеми, наноматеріали, нанотехнології. - 2012. - Т. 10, Вип. 1. - С. 123-133. - Режим доступу: http://nbuv.gov.ua/UJRN/Nano_2012_10_1_17","otherReferences":"Smolyak Svitlana; Karbivskyy Volodymyr, 2025, \"Study of the electronic structure of Mn₂₋ₓCoₓP₂O₇·5H₂O at x=0.6, using X-ray photoelectron spectroscopy\", https://doi.org/10.48788/DVUA/RROGBK, DataverseUA","citation:productionPlace":"Kyiv, Ukraine","grantNumber":{"citation:grantNumberAgency":"NAS of Ukraine"},"citation:producer":{"citation:producerName":"Kurdyumov Institute for Metal Physics","citation:producerAffiliation":"NAS of Ukraine","citation:producerAbbreviation":"IMP","citation:producerURL":"https://www.imp.kiev.ua","citation:producerLogoURL":"https://www.imp.kiev.ua/img/header_ua.jpg"},"language":"English","citation:series":{"citation:seriesName":"Spectroscopy dataset"},"kindOfData":"Spectra – processed experimental spectrum","timePeriodCovered":{"citation:timePeriodCoveredStart":"2009-01-28","citation:timePeriodCoveredEnd":"2009-01-29"},"@id":"https://doi.org/10.48788/DVUA/XQK99H","@type":["ore:Aggregation","schema:Dataset"],"schema:version":"1.0","schema:name":"X-ray photoelectron spectroscopic study of the electronic structure of Mn₂₋ₓCoₓP₂O₇·5H₂O, at x=1.0","schema:dateModified":"2025-11-21 14:49:22.421","schema:datePublished":"2025-11-21","schema:creativeWorkStatus":"RELEASED","schema:license":"http://creativecommons.org/licenses/by/4.0","dvcore:fileTermsOfAccess":{"dvcore:fileRequestAccess":true},"schema:includedInDataCatalog":"DataverseUA","schema:isPartOf":{"schema:name":"SPM&RS Centre","@id":"https://opendata.nas.gov.ua/dataverse/spm","schema:description":"The collective use centre \"Centre of scanning probe microscopy and resonance spectroscopy\" (SPM&RS-Centre) was created in 2012 in the structure of the G. 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