{"id":1093,"identifier":"DVUA/MNVHJZ","persistentUrl":"https://doi.org/10.48788/DVUA/MNVHJZ","protocol":"doi","authority":"10.48788","publisher":"DataverseUA","publicationDate":"2026-03-27","storageIdentifier":"local://10.48788/DVUA/MNVHJZ","datasetVersion":{"id":94,"datasetId":1093,"datasetPersistentId":"doi:10.48788/DVUA/MNVHJZ","storageIdentifier":"local://10.48788/DVUA/MNVHJZ","versionNumber":1,"versionMinorNumber":0,"versionState":"RELEASED","productionDate":"2019","lastUpdateTime":"2026-03-27T13:46:28Z","releaseTime":"2026-03-27T13:46:28Z","createTime":"2026-03-23T13:49:17Z","publicationDate":"2026-03-27","citationDate":"2026-03-27","license":{"name":"CC BY 4.0","uri":"http://creativecommons.org/licenses/by/4.0","iconUri":"https://licensebuttons.net/l/by/4.0/88x31.png"},"termsOfAccess":"Contact owner","fileAccessRequest":true,"metadataBlocks":{"citation":{"displayName":"Citation Metadata","name":"citation","fields":[{"typeName":"title","multiple":false,"typeClass":"primitive","value":"X-ray photoelectron and Nuclear Magnetic Resonance studies of sol-gel glass doped with 5% Ga"},{"typeName":"author","multiple":true,"typeClass":"compound","value":[{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Smolyak Svitlana"},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"SPM&RS Centre"},"authorIdentifierScheme":{"typeName":"authorIdentifierScheme","multiple":false,"typeClass":"controlledVocabulary","value":"ORCID"},"authorIdentifier":{"typeName":"authorIdentifier","multiple":false,"typeClass":"primitive","value":"0000-0002-5403-4092"}},{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Karbivskyy Volodymyr"},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"SPM&RS Centre"},"authorIdentifierScheme":{"typeName":"authorIdentifierScheme","multiple":false,"typeClass":"controlledVocabulary","value":"ORCID"},"authorIdentifier":{"typeName":"authorIdentifier","multiple":false,"typeClass":"primitive","value":"0000-0003-0412-2788"}},{"authorName":{"typeName":"authorName","multiple":false,"typeClass":"primitive","value":"Zagorodniy Yuriy"},"authorAffiliation":{"typeName":"authorAffiliation","multiple":false,"typeClass":"primitive","value":"I.M.Frantsevich Institute for Problems in Material Science of the NAS. of Ukraine,Kyiv, Ukraine"},"authorIdentifierScheme":{"typeName":"authorIdentifierScheme","multiple":false,"typeClass":"controlledVocabulary","value":"ORCID"},"authorIdentifier":{"typeName":"authorIdentifier","multiple":false,"typeClass":"primitive","value":"0000-0002-0404-5041"}}]},{"typeName":"datasetContact","multiple":true,"typeClass":"compound","value":[{"datasetContactName":{"typeName":"datasetContactName","multiple":false,"typeClass":"primitive","value":"Smolyak, Svitlana"},"datasetContactAffiliation":{"typeName":"datasetContactAffiliation","multiple":false,"typeClass":"primitive","value":"SPM&RS Centre"},"datasetContactEmail":{"typeName":"datasetContactEmail","multiple":false,"typeClass":"primitive","value":"sssmolyak@gmail.com"}}]},{"typeName":"dsDescription","multiple":true,"typeClass":"compound","value":[{"dsDescriptionValue":{"typeName":"dsDescriptionValue","multiple":false,"typeClass":"primitive","value":"The electronic structure and structural characteristics of 5% Ga-doped sol-gel bioactive glass (type 45S5) were studied by X-ray photoelectron spectroscopy (XPS) and nuclear magnetic resonance (NMR) methods.  ³¹P NMR spectra of bioactive materials indicate the formation of both isolated (PO4)3- and Si-O-P bonds, etc. in them, the relative part of which is proportional to the integral intensity of the corresponding NMR line.\nThe synthesis of the samples was carried out by Doctor of Chemical Sciences Vitaliy A. 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The principles of nuclear magnetism.  Oxford, Clarendon Press, 1962"}},{"keywordValue":{"typeName":"keywordValue","multiple":false,"typeClass":"primitive","value":"Bioactive glass"},"keywordVocabulary":{"typeName":"keywordVocabulary","multiple":false,"typeClass":"primitive","value":"Wikipedia"},"keywordVocabularyURI":{"typeName":"keywordVocabularyURI","multiple":false,"typeClass":"primitive","value":"https://en.wikipedia.org/wiki/Bioactive_glass"}}]},{"typeName":"publication","multiple":true,"typeClass":"compound","value":[{"publicationCitation":{"typeName":"publicationCitation","multiple":false,"typeClass":"primitive","value":"Svitlana S. Smolyak, Volodymyr L. Karbivskyy, Vitaliy A. Dubok, Volodymyr S. Chornyi, Olexander V. Shynkaruk, Anastas O. Romansky, Lyubov I. Karbivska. New bone substitute based on nanodispersed calcium ceramics. Ukr. Bioorg. Acta, 2023, Vol. 18, N 1, p. 42-50."},"publicationIDType":{"typeName":"publicationIDType","multiple":false,"typeClass":"controlledVocabulary","value":"doi"},"publicationIDNumber":{"typeName":"publicationIDNumber","multiple":false,"typeClass":"primitive","value":"https://bioorganica.com.ua/index.php/journal/article/view/58"},"publicationURL":{"typeName":"publicationURL","multiple":false,"typeClass":"primitive","value":"https://bioorganica.com.ua/index.php/journal/article/view/58"}}]},{"typeName":"notesText","multiple":false,"typeClass":"primitive","value":"X-ray  photoelectron spectra (XPS) were obtained on a JEOL JSPM-4610 photoelectron spectrometer using a non-monochromatic MgKα  X-ray source (1253.6eV). During the experiment, the vacuum in the analytical chamber  was   10⁻⁷ Pa, and the electron binding energy determination accuracy was 0.1. The samples for the study were prepared as dispersed powders deposited on an aluminum substrate.  A  thin gold layer was deposited on the insulating surface of the sample to prevent charge accumulation during the experiment. The X-ray photoelectron spectra were calibrated by the binding energy of Au 4f lines, which enabled high-precision determination of the electron binding energy for the elements in the sample. \nNuclear magnetic resonance (NMR)  spectra  were recorded  on  a  Bruker  Avance400  spectrometer  at  room  temperature.  ³¹P NMR  spectra were obtained  for static  samples (at a frequency 161,97  MHz). The  magnetic  field  was referenced  by  the  H₃PO₄ spectrum,  which  was  used  as  an external standard for magnetic field calibration."},{"typeName":"language","multiple":true,"typeClass":"controlledVocabulary","value":["English"]},{"typeName":"producer","multiple":true,"typeClass":"compound","value":[{"producerName":{"typeName":"producerName","multiple":false,"typeClass":"primitive","value":"G. V. Kurdyumov Institute for Metal Physics"},"producerAffiliation":{"typeName":"producerAffiliation","multiple":false,"typeClass":"primitive","value":"N.A.S. of Ukraine"},"producerAbbreviation":{"typeName":"producerAbbreviation","multiple":false,"typeClass":"primitive","value":"IMP"},"producerURL":{"typeName":"producerURL","multiple":false,"typeClass":"primitive","value":"https://www.imp.kiev.ua/"},"producerLogoURL":{"typeName":"producerLogoURL","multiple":false,"typeClass":"primitive","value":"https://www.imp.kiev.ua/img/header_ua.jpg"}}]},{"typeName":"productionDate","multiple":false,"typeClass":"primitive","value":"2019"},{"typeName":"productionPlace","multiple":true,"typeClass":"primitive","value":["Kyiv, Ukraine"]},{"typeName":"contributor","multiple":true,"typeClass":"compound","value":[{"contributorType":{"typeName":"contributorType","multiple":false,"typeClass":"controlledVocabulary","value":"Research Group"},"contributorName":{"typeName":"contributorName","multiple":false,"typeClass":"primitive","value":"SPM&RS Centre"}}]},{"typeName":"grantNumber","multiple":true,"typeClass":"compound","value":[{"grantNumberAgency":{"typeName":"grantNumberAgency","multiple":false,"typeClass":"primitive","value":"NAS of Ukraine"}}]},{"typeName":"depositor","multiple":false,"typeClass":"primitive","value":"Smolyak Svitlana"},{"typeName":"dateOfDeposit","multiple":false,"typeClass":"primitive","value":"2026-03-23"},{"typeName":"kindOfData","multiple":true,"typeClass":"primitive","value":["Spectra – processed experimental spectrum"]},{"typeName":"series","multiple":true,"typeClass":"compound","value":[{"seriesName":{"typeName":"seriesName","multiple":false,"typeClass":"primitive","value":"Spectroscopy dataset"}}]}]}},"files":[{"description":" ³¹P NMR static spectra of sol-gel bioactive glass doped with 5% Ga. 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