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analyzed through X-ray photoelectron spectroscopy."},"dsDescriptionDate":{"typeName":"dsDescriptionDate","multiple":false,"typeClass":"primitive","value":"2025-10-28"}}]},{"typeName":"subject","multiple":true,"typeClass":"controlledVocabulary","value":["Physics"]},{"typeName":"keyword","multiple":true,"typeClass":"compound","value":[{"keywordValue":{"typeName":"keywordValue","multiple":false,"typeClass":"primitive","value":"X-ray Photoelectron Spectroscopy"},"keywordVocabulary":{"typeName":"keywordVocabulary","multiple":false,"typeClass":"primitive","value":"Montana State University"},"keywordVocabularyURI":{"typeName":"keywordVocabularyURI","multiple":false,"typeClass":"primitive","value":"https://serc.carleton.edu/msu_nanotech/methods/xps.html"}},{"keywordValue":{"typeName":"keywordValue","multiple":false,"typeClass":"primitive","value":"Electronic 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L. Karbivskyy, S. S. Smolyak, Yu. A. Zagorodniy, V. H. Kasiyanenko. Electronic structure peculiarities of disordered of Mn and Co diphosphates. Functional Materials, 2012, 19, №4, p.459-463"},"publicationURL":{"typeName":"publicationURL","multiple":false,"typeClass":"primitive","value":"http://functmaterials.org.ua/contents/19-4/fm194-08.pdf"}}]},{"typeName":"notesText","multiple":false,"typeClass":"primitive","value":"X-ray photoelectron spectra (XPS) of the sample - Mn₂₋ₓCoₓP₂O₇·5H₂O, at x=1.0, have been obtained on the photoelectron spectrometer of firm \"JEOL\" - “JSPM-4610” with the use of the non-monochromatic Al Kα (1486.6 eV) X-ray source. During the experiment, the vacuum in the analytical chamber was 10-7 Pa, the accuracy of the electrons binding energy definition - 0.1 eV. The samples were in the form of dispersed powder deposited on an aluminum substrate. Because the investigated samples are insulators, the emission of electrons during the spectrum acquisition led to the formation of a positive electrical charge on their surface and to an essential shift of corresponding lines. Calibration of X-ray photoelectron spectra taking into account the accumulated charge, were carried by the binding energy of 1s-level of carbon, which was accepted equal to 284.4 eV. The synthesis of the samples was carried out by Candidate of Chemical Sciences Tkachova N.V."},{"typeName":"language","multiple":true,"typeClass":"controlledVocabulary","value":["English"]},{"typeName":"producer","multiple":true,"typeClass":"compound","value":[{"producerName":{"typeName":"producerName","multiple":false,"typeClass":"primitive","value":"Kurdyumov Institute for Metal Physics"},"producerAffiliation":{"typeName":"producerAffiliation","multiple":false,"typeClass":"primitive","value":"NAS of Ukraine"},"producerAbbreviation":{"typeName":"producerAbbreviation","multiple":false,"typeClass":"primitive","value":"IMP"},"producerURL":{"typeName":"producerURL","multiple":false,"typeClass":"primitive","value":"https://www.imp.kiev.ua"},"producerLogoURL":{"typeName":"producerLogoURL","multiple":false,"typeClass":"primitive","value":"https://www.imp.kiev.ua/img/header_ua.jpg"}}]},{"typeName":"productionPlace","multiple":true,"typeClass":"primitive","value":["Kyiv, Ukraine"]},{"typeName":"contributor","multiple":true,"typeClass":"compound","value":[{"contributorType":{"typeName":"contributorType","multiple":false,"typeClass":"controlledVocabulary","value":"Research Group"},"contributorName":{"typeName":"contributorName","multiple":false,"typeClass":"primitive","value":"SPM&RS Centre"}}]},{"typeName":"grantNumber","multiple":true,"typeClass":"compound","value":[{"grantNumberAgency":{"typeName":"grantNumberAgency","multiple":false,"typeClass":"primitive","value":"NAS of Ukraine"}}]},{"typeName":"depositor","multiple":false,"typeClass":"primitive","value":"Smolyak Svitlana"},{"typeName":"dateOfDeposit","multiple":false,"typeClass":"primitive","value":"2025-10-28"},{"typeName":"timePeriodCovered","multiple":true,"typeClass":"compound","value":[{"timePeriodCoveredStart":{"typeName":"timePeriodCoveredStart","multiple":false,"typeClass":"primitive","value":"2009-01-28"},"timePeriodCoveredEnd":{"typeName":"timePeriodCoveredEnd","multiple":false,"typeClass":"primitive","value":"2009-01-29"}}]},{"typeName":"kindOfData","multiple":true,"typeClass":"primitive","value":["Spectra – processed experimental spectrum"]},{"typeName":"series","multiple":true,"typeClass":"compound","value":[{"seriesName":{"typeName":"seriesName","multiple":false,"typeClass":"primitive","value":"Spectroscopy dataset"}}]},{"typeName":"relatedMaterial","multiple":true,"typeClass":"primitive","value":["В. Л. Карбовский, С. С. Смоляк, Ю. А. Загородний, В. Х. Касияненко, Н. В. Ткачова, О. П. Димитриев. Колебательные спектры и термические превращения дифосфатов Mn₂₋ₓCoₓP₂O₇·5H₂O. Наносистеми, наноматеріали, нанотехнології. - 2012. - Т. 10, Вип. 1. - С. 123-133. - Режим доступу: http://nbuv.gov.ua/UJRN/Nano_2012_10_1_17"]},{"typeName":"relatedDatasets","multiple":true,"typeClass":"primitive","value":["Smolyak Svitlana; Karbivskyy Volodymyr, 2025, \"Study of Mn₂₋ₓCoₓP₂O₇·5H₂O, at x=0, using X-ray photoelectron spectroscopy\", https://doi.org/10.48788/DVUA/0YSLVZ, DataverseUA"]},{"typeName":"otherReferences","multiple":true,"typeClass":"primitive","value":["Smolyak Svitlana; Karbivskyy Volodymyr, 2025, \"Study of the electronic structure of Mn₂₋ₓCoₓP₂O₇·5H₂O at x=0.6, using X-ray photoelectron spectroscopy\", https://doi.org/10.48788/DVUA/RROGBK, DataverseUA"]}]}},"files":[{"description":"X-ray photoelectron Со 2р spectrum for the Mn2-хCoxP2O7·5H2O, x=1.0. S – satellite. 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