<?xml version='1.0' encoding='UTF-8'?><codeBook xmlns="ddi:codebook:2_5" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="ddi:codebook:2_5 https://ddialliance.org/Specification/DDI-Codebook/2.5/XMLSchema/codebook.xsd" version="2.5"><docDscr><citation><titlStmt><titl>XPS experiment dataset for crystal Tl3PbBr5</titl><IDNo agency="DOI">doi:10.48788/DVUA/IVKESW</IDNo></titlStmt><distStmt><distrbtr source="archive">DataverseUA</distrbtr><distDate>2023-10-06</distDate></distStmt><verStmt source="archive"><version date="2024-11-25" type="RELEASED">1</version></verStmt><biblCit>O.Y. Khyzhun; N. M. Denysyuk, 2023, "XPS experiment dataset for crystal Tl3PbBr5", https://doi.org/10.48788/DVUA/IVKESW, DataverseUA, V1</biblCit></citation></docDscr><stdyDscr><citation><titlStmt><titl>XPS experiment dataset for crystal Tl3PbBr5</titl><IDNo agency="DOI">doi:10.48788/DVUA/IVKESW</IDNo></titlStmt><rspStmt><AuthEnty affiliation="Frantsevych Institute for Problems of Materials Science of NAS of Ukraine">O.Y. Khyzhun</AuthEnty><AuthEnty affiliation="Frantsevych Institute for Problems of Materials Science of NAS of Ukraine">N. M. Denysyuk</AuthEnty><othId role="Data Collector">Denysyuk Natalia</othId></rspStmt><prodStmt><prodDate>2012-10-02</prodDate></prodStmt><distStmt><distrbtr source="archive">DataverseUA</distrbtr><contact affiliation="Frantsevych Institute for Problems of Materials Science of NAS of Ukraine" email="denisyuck.natalia@gmail.com">O.Y. Khyzhun</contact><distDate>2013-03-10</distDate><depositr>Denysyuk Natalia</depositr><depDate>2022-02-06</depDate></distStmt><holdings URI="https://doi.org/10.48788/DVUA/IVKESW"/></citation><stdyInfo><subject><keyword xml:lang="en">Chemistry</keyword><keyword xml:lang="en">Physics</keyword><keyword vocab="Medical Subject Headings" vocabURI="http://purl.bioontology.org/ontology/MESH/D012666">Semiconductors</keyword><keyword vocab="Semanticscience Integrated Ontology" vocabURI="http://semanticscience.org/resource/SIO_001099">electronic structure</keyword><keyword vocab="Chemical Methods Ontology" vocabURI="http://purl.obolibrary.org/obo/CHMO_0002224">crystal growth method</keyword><keyword vocab="National Cancer Institute Thesaurus" vocabURI="http://ncicb.nci.nih.gov/xml/owl/EVS/Thesaurus.owl#C78871">X-ray photoelectron spectroscopy</keyword></subject><abstract date="2012-10-02">The X-ray photoelectron core-level and valence-band spectra for pristine and Ar+-ion irradiated surfaces of a Tl3PbBr5 single crystal grown by the Bridgman–Stockbarger method have been measured. The present X-ray photoelectron spectroscopy (XPS) results reveal high chemical stability of Tl3PbBr5 single crystal surface.</abstract><sumDscr><collDate cycle="P1" event="start" date="2012-10-02">2012-10-02</collDate><collDate cycle="P1" event="end" date="2012-10-03">2012-10-03</collDate><dataKind>XPS experiment dataset</dataKind></sumDscr><notes>Preparation, etching regimes
I (etching current) 17 A; V (etching voltage) 3 kV; t (etching time) 5 min; P (etching pressure) 8x10-6 mbar; theta (etching angle) 55; Preparation Ex-situ No; Preparation In-situ Ion beam cleaned with 3 kV Ar ions.
Analysis source characteristic energy 1253.6 eV; analysis source power (power) 100 W; analysis source strength
(emission current) 100 mA; analysis source strength; (anode voltage) 10 kV; analysis pass energy 30 eV; analysis chamber pressure 4x10-10 mbar; start energy (Kinetic Energy) Spectrum start kinetic energy; end energy (Kinetic Energy) Spectrum end kinetic energy; start energy (Binding Energy) 1000; end energy (Binding Energy) -10 eV; eV per step 0.1; Dwell time 0.1; Source Angle 45; Analyzer axis take off polar; angle 90 deg; the angle of inclination of the source to the plane of the sample at measurements of 55 deg</notes></stdyInfo><method><dataColl><sources/></dataColl><anlyInfo/></method><dataAccs><setAvail/><useStmt/></dataAccs><othrStdyMat><relPubl><citation><titlStmt><IDNo agency="doi">10.1016/j.optmat.2012.12.008</IDNo></titlStmt><biblCit>O.Y.Khyzhun, V.L.Bekenev, O.V.Parasyuk, S.P.Danylchuk, N.M.Denysyuk, A.O.Fedorchuk, N.AlZayed, I.V.Kityk / Single crystal growth and the electronic structure of orthorhombic Tl3PbBr5: A novel material for non-linear optics // Optical Materials - Volume 35, Issue 5, 2013, P. 1081-1089</biblCit></citation><ExtLink URI="https://doi.org/10.1016/j.optmat.2012.12.008"/></relPubl></othrStdyMat></stdyDscr><otherMat ID="f13" URI="https://doi.org/10.48788/DVUA/IVKESW/LKVKHZ" level="datafile"><labl>Tl3PbBr5-4d.txt</labl><txt>contains data obtained for common 4d - electrons, uncoated surface</txt><notes level="file" type="DATAVERSE:CONTENTTYPE" subject="Content/MIME Type">text/plain</notes></otherMat><otherMat ID="f11" URI="https://doi.org/10.48788/DVUA/IVKESW/WVBJ6U" level="datafile"><labl>Tl3PbBr5-4f.txt</labl><txt>contains data obtained for total 4f - electrons, uncoated surface</txt><notes level="file" type="DATAVERSE:CONTENTTYPE" subject="Content/MIME Type">text/plain</notes></otherMat><otherMat ID="f19" URI="https://doi.org/10.48788/DVUA/IVKESW/QAIHPY" level="datafile"><labl>Tl3PbBr5-Ar_4d.txt</labl><txt>contains data obtained for total 4d - electrons, after surface treatment with argon</txt><notes level="file" type="DATAVERSE:CONTENTTYPE" subject="Content/MIME Type">text/plain</notes></otherMat><otherMat ID="f20" URI="https://doi.org/10.48788/DVUA/IVKESW/VYGV9L" level="datafile"><labl>Tl3PbBr5-Ar_4f.txt</labl><txt>contains data obtained for total 4f - electrons after surface treatment with argon</txt><notes level="file" type="DATAVERSE:CONTENTTYPE" subject="Content/MIME Type">text/plain</notes></otherMat><otherMat ID="f16" URI="https://doi.org/10.48788/DVUA/IVKESW/MYYXVF" level="datafile"><labl>Tl3PbBr5-Ar_Br_3d.txt</labl><txt>contains data obtained for Br 3d – electrons, after surface treatment with argon</txt><notes level="file" type="DATAVERSE:CONTENTTYPE" subject="Content/MIME Type">text/plain</notes></otherMat><otherMat ID="f22" URI="https://doi.org/10.48788/DVUA/IVKESW/5Z68D0" level="datafile"><labl>Tl3PbBr5-Ar_Br_p.txt</labl><txt>- contains data obtained for Br p - electrons after surface treatment with argon</txt><notes level="file" type="DATAVERSE:CONTENTTYPE" subject="Content/MIME Type">text/plain</notes></otherMat><otherMat ID="f18" URI="https://doi.org/10.48788/DVUA/IVKESW/TEVCJX" level="datafile"><labl>Tl3PbBr5-Ar_C1s.txt</labl><txt>contains data obtained for C 1s - electrons, after surface treatment with argon</txt><notes level="file" type="DATAVERSE:CONTENTTYPE" subject="Content/MIME Type">text/plain</notes></otherMat><otherMat ID="f21" URI="https://doi.org/10.48788/DVUA/IVKESW/8G4ORR" level="datafile"><labl>Tl3PbBr5-Ar_Survey.txt</labl><txt>contains general data obtained after surface treatment with argon</txt><notes level="file" type="DATAVERSE:CONTENTTYPE" subject="Content/MIME Type">text/plain</notes></otherMat><otherMat ID="f10" URI="https://doi.org/10.48788/DVUA/IVKESW/ITNN5E" level="datafile"><labl>Tl3PbBr5-Ar_VB.txt</labl><txt>contains data obtained for valence band electrons after surface treatment with argon</txt><notes level="file" type="DATAVERSE:CONTENTTYPE" subject="Content/MIME Type">text/plain</notes></otherMat><otherMat ID="f14" URI="https://doi.org/10.48788/DVUA/IVKESW/7MTAAP" level="datafile"><labl>Tl3PbBr5-Br_3d.txt</labl><txt>contains data obtained for Br 3d - electrons, uncoated surface</txt><notes level="file" type="DATAVERSE:CONTENTTYPE" subject="Content/MIME Type">text/plain</notes></otherMat><otherMat ID="f17" URI="https://doi.org/10.48788/DVUA/IVKESW/AE6UJA" level="datafile"><labl>Tl3PbBr5-Br_p.txt</labl><txt>contains data obtained for Br p - electrons, uncoated surface</txt><notes level="file" type="DATAVERSE:CONTENTTYPE" subject="Content/MIME Type">text/plain</notes></otherMat><otherMat ID="f15" URI="https://doi.org/10.48788/DVUA/IVKESW/UOZEUJ" level="datafile"><labl>Tl3PbBr5-C1s.txt</labl><txt>contains data obtained for C 1s - electrons, uncoated surface</txt><notes level="file" type="DATAVERSE:CONTENTTYPE" subject="Content/MIME Type">text/plain</notes></otherMat><otherMat ID="f12" URI="https://doi.org/10.48788/DVUA/IVKESW/RWDDK5" level="datafile"><labl>Tl3PbBr5-VB.txt</labl><txt>contains data obtained for electrons of the valence band of the uncoated surface</txt><notes level="file" type="DATAVERSE:CONTENTTYPE" subject="Content/MIME Type">text/plain</notes></otherMat><otherMat ID="f43" URI="https://doi.org/10.48788/DVUA/IVKESW/P2MHSC" level="datafile"><labl>Tl3PbBr5_Survey.txt</labl><txt>contains general data obtained for an uncoated surface</txt><notes level="file" type="DATAVERSE:CONTENTTYPE" subject="Content/MIME Type">text/plain</notes></otherMat></codeBook>